Behavior of Major and Trace Elements during Ore Deposition: Example from the Low-Sulfidation Pantingan Gold System, Mount Mariveles, Bataan, Philippines     

Betchaida D. Payot    Rodolfo A. Tamayo  Jr  Victor B. Maglambayan    Carla B. Dimalanta    Graciano P. Yumul  Jr  Shigeyuki Suzuki  Mei-Fu Zhou 《Resource Geology》2007,57(2):180-196

The evaluation of the relatively fresh host rock and altered rock samples associated with the Pantingan Gold System exposed in Mount Mariveles, Bataan yield several notable observations that are useful in pinpointing potential gold pathfinder elements. Geochemical and petrologic analysis showed that the altered rocks can be subdivided into rocks that underwent propylitic alteration (group 1), argillized rocks with silica contents similar to those of the fresh host rocks (group 2), argillized but not strongly silicified rocks (group 3) and argillized and strongly silicified rocks (group 4). Selected element ratio patterns in the altered rocks and gold concentrations in gold‐bearing quartz veins vary between the rock groups. Moreover, mass balance calculation also reflected the geochemical observations pertaining to the gains and losses of SiO_2, Fe₂O₃+ MgO, CaO + Na₂O and K₂O, which are believed to be chemical reactions (i.e. breakdown of plagioclase, silica inundation or leaching, sulfide and calcite formation) caused by the influx of hydrothermal fluids.  相似文献   

Temporal Geochemical Evolution of Neogene Magmatism in the Baguio Gold–Copper Mining District (Northern Luzon, Philippines)     

Mireille Polve    Rene C. Maury    Sebastien Jego    Herve Bellon    Ahmed Margoum    Graciano P. Yumul  Jr  Betchaida D. Payot    Rodolfo A. Tamayo  Jr Joseph Cotten 《Resource Geology》2007,57(2):197-218

Baguio, in the Central Cordillera of Northern Luzon, is a district that displays porphyry copper and epithermal gold mineralization, associated with Early Miocene–Pliocene–Quaternary calc‐alkaline and adakitic intrusions. Systematic sampling, K‐Ar dating, major and trace elements, and Sr, Nd, Pb isotopic analyses of fresh magmatic rocks indicate three magmatic pulses: an Early Miocene phase (21.2–18.7 Ma), a Middle–Late Miocene phase (15.3–8 Ma) and finally a Pliocene–Quaternary event (3–1 Ma). The first phase emplaced evolved calc‐alkaline magmas, essentially within the Agno Batholith complex, and is thought to be related to the westward‐dipping subduction of the West Philippine Basin. After a quiescence period during which the Kennon limestone was deposited, magmatic activity resumed at 15.3 Ma, in connection with the start of the subduction of the South China Sea along the Manila Trench. It emplaced first petrogenetically related and relatively unradiogenic low‐K calc‐alkaline lavas and intermediate adakites. Temporal geochemical patterns observed from 15.3 to 1 Ma include progressive enrichment in K and other large ion lithophile elements, increase in radiogenic Sr and Pb and corresponding decrease in radiogenic Nd. These features are thought to reflect the progressive addition to the Luzon arc mantle wedge of incompatible elements largely inherited from South China Sea sediments. The origin of the long quiescence period, from 8 to 3 Ma, remains problematic. It might represent a local consequence of the docking of the Zambales ophiolitic terrane to Northern Luzon. Then, magmatic activity resumed at 3 Ma, emplacing chemically diversified rocks ranging from low K to high K and including a large proportion of adakites, especially during the Quaternary (dacitic plugs). The authors tentatively relate this diversity to the development of a slab tear linked with the subduction of the fossil South China Sea ridge beneath the Baguio area.  相似文献   

Anomalous Emissions of SO2 During the Recent Eruption of Santa Ana Volcano, El Salvador, Central America   总被引：1，自引：0，他引：1  

Rodolfo Olmos  José Barrancos  Claudia Rivera  Francisco Barahona  Dina L. López  Benancio Henriquez  Agustín Hernández  Efrain Benitez  Pedro A. Hernández  Nemesio M. Pérez  Bo Galle 《Pure and Applied Geophysics》2007,164(12):2489-2506

Santa Ana volcano in western El Salvador, Central America, had a phreatic eruption at 8:05 am (local time) on October 1, 2005, 101 years after its last eruption. However, during the last one hundred years this volcano has presented periods of quiet degassing with fumarolic activity and an acidic lake within its crater. This paper presents results of frequent measurements of SO₂ degassing using the MiniDOAS (Differential Optical Absorption Spectroscopy) system and a comparison with the volcanic seismicity prior to the eruption, during, and after the eruption. Vehicle measurements of SO₂ flux were taken every hour during the first nine days of the eruption and daily after that. The period of time reported here is from August to December, 2005. Three periods of degassing are distinguished: pre-eruptive, eruptive, and post-eruptive periods. The intense activity at Santa Ana volcano started in July 2005. During the pre-eruptive period up to 4306 and 5154 ton/day of SO₂ flux were recorded on October 24 and September 9, 2005, respectively. These values were of the same order of magnitude as the recorded values just after the October 1^st eruption (2925 ton/day at 10:01 am). Hourly measurements of SO₂ flux taken during the first nine days after the main eruptive event indicate that explosions are preceded by an increase in SO₂ flux and that this parameter reaches a peak after the explosion took place. This behavior suggests that increasing accumulation of exsolved magmatic gases occurs within the magmatic chamber before the explosions, increasing the pressure until the point of explosion. A correlation between SO₂ fluxes and RSAM (Real Time Seismic Amplitude Measurements) is observed during the complete sampling period. Periodic fluctuations in the SO₂ and RSAM values during the entire study period are observed. One possible mechanism explaining these fluctuations it that convective circulation within the magmatic chamber can bring fresh magma periodically to shallow levels, allowing increasing degasification and then decreasing degasification as the batch of magma lowers its gas content, becomes denser, and sinks to give space to a new magma pulse. These results illustrate that the measurements of SO₂ flux can provide important warning signals for incoming explosive activity in active volcanoes.  相似文献   

Characterizing rainfall‐runoff signatures from micro‐catchments with contrasting land cover characteristics in southern Amazonia          下载免费PDF全文

Alphonce C. Guzha  Rodolfo L. B. Nobrega  Kristof Kovacs  Jessica Rebola‐Lichtenberg  Ricardo S. S. Amorim  Gerhard Gerold 《水文研究》2015,29(4):508-521

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Italian strong motion records in ITACA: overview and record processing     

Francesca Pacor  Roberto Paolucci  Gabriele Ameri  Marco Massa  Rodolfo Puglia 《Bulletin of Earthquake Engineering》2011,9(6):1741-1759

The published version 1.0 of the new Italian strong-motion database ITACA (Italian ACcelerometric Archive, ) includes to date (December 2010) about 4,000 three-component waveforms up to M 6.9, from more than 1,800 earthquakes up to 6.9, recorded by about 400 stations in the period 1972–2009. The uncorrected and corrected strong motion data are archived and can be retrieved with their metadata, concerning events, stations and waveforms. The aim of this paper is to present the procedures for processing the records included in ITACA, accounting for the heterogeneity of this data set, both in terms of quality and amplitude of records as well as illustrating the main features of the ITACA strong-motion dataset. Later, we focus on the “exceptional” ground-motion records, that we, conventionally, denote as those having peak acceleration and peak velocity larger than 300 cm/s² and 15 cm/s, respectively. These records are less than 2% of the whole ITACA dataset but they are the most relevant for the seismic hazard and engineering implications. Such large peak values, recorded at distances up to 30 km, are related not only to the strongest Italian earthquakes, but also to events with magnitude down to 4. Furthermore, we investigate the dependence of the largest peak values on horizontal and vertical directions and on source-to-site distance.  相似文献   

Comparison of Two Sample Preparation Methods for X‐Ray Fluorescence Spectrometry in the Determination of Ni and Cr     

Surendra P. Verma  Rosalinda González‐Ramírez  Rodolfo Rodríguez‐Ríos 《Geostandards and Geoanalytical Research》2011,35(2):183-192

Pressed powder pellets and fused beads or glass disks are routinely used in X‐ray fluorescence spectrometry for the determination of major and trace elements, respectively, in geological materials. In order to evaluate the performance of these two sample preparation methods, we determined Ni and Cr concentrations of fourteen RMs from Japan, France and South Africa, and eighty‐five igneous and three sedimentary rock samples from Mexico in both powder pellets and glass beads. We also computed new values of statistical parameters for RMs from an outlier‐based multiple‐test method and compared them with the literature mean and confidence limit values. The results showed that the multiple‐test method provided more reliable central tendency and dispersion parameters for RMs than those obtained previously from the two or three standard deviation method, or from robust methods. The powder pellet and fused bead sample preparation methods provided consistent results for Ni and Cr at concentration levels > 50 μg g^?1 in this application; for lower concentration levels, however, these methods showed somewhat greater differences. For quantitative comparisons, both ordinary and weighted least‐squares linear regression models were used to show that the two sample preparation methods provided generally unbiased results.  相似文献   

Atmospheric models of He-peculiar stars: synthetic He I line profiles and absolute visual magnitudes     

Rodolfo Vallverdú  Lydia Cidale  René Rohrmann  Adela Ringuelet 《Astrophysics and Space Science》2014,352(1):95-102

We analyze the influence of magnetic pressure effects on the atmospheric structure of B peculiar type stars, as well as, on the emergent He?I line profiles and absolute visual magnitudes. We consider a photosphere in local thermodynamic and hydrostatic equilibrium. The hydrostatic equilibrium equation is modified to include the Lorentz force. Atomic occupational numbers are computed in LTE considering non-ideal effects in the gas equation of state. We depict the influence of a magnetic field on local He?I line profiles and discuss the effects of the helium abundance in magnetic B-type stars. The Lorentz force might explain local variations up to 7 % in the equivalent width of helium lines, while local enhancements of He chemical abundances would produce larger changes. To analyze the line variations in real stars we computed the net contribution of a bipolar magnetic field over the stellar disk. The resulting disk-averaged magnetic field predicts variations with the rotation phase up to 2–3 % in the line EWs for a dipolar magnetic field of 1000 G.  相似文献   

Process Contribution to the Time-Varying Residual Circulation in Tidally Dominated Estuarine Environments     

Jennifer M. Brown  Rodolfo Bolaños  Alejandro J. Souza 《Estuaries and Coasts》2014,37(5):1041-1057

In tide-dominated environments, residual circulation is the comparatively weak net flow in addition to the oscillatory tidal current. Understanding the 3D structure of this circulation is of importance for coastal management as it impacts the net (longer term and event-scale) transport of suspended particles and the advection of tracer quantities. The Dee Estuary, northwest Britain, is used to understand which physical processes have an important contribution to the time-varying residual circulation. Model simulations are used to extract the time-varying contributions of tidal, riverine (baroclinicity and discharge), meteorological, external and wave processes, along with their interactions. Under hypertidal conditions, strong semi-diurnal interaction within the residual makes it difficult to clearly see the effect of a process without filtering. An approach to separate the residual into the isolated process contribution and the contribution due to interaction is described. Applying this method to two hypertidal estuarine channels, one tide dominant and one baroclinic dominant, reveals that process interaction can be as important as the sub-tidal residual process contributions themselves. The time variation of the residual circulation highlights the impact of different physical process components at the event scale of tidal conditions (neap and spring cycles) and offshore storms (wind, wave and surge influence). This gives insight into short-term deviation from the typical estuarine residual. Both channels are found to react differently to the same local conditions, with different short-term change in process dominance during events of high and low energy.  相似文献   

Soil discrimination using diffuse reflectance Vis–NIR spectroscopy in a local toposequence     

José Francirlei Oliveira  Michel Brossard  Pedro Rodolfo Siqueira Vendrame  Stanislas Mayi III  Edemar Joaquim Corazza  Robélio Leandro Marchão  Maria de Fátima Guimarães 《Comptes Rendus Geoscience》2013,345(11-12):446-453

Vis–NIR spectroscopy is nowadays presented as a possible routine method for soil sample analysis. However, there is still no consensus on which is the best multivariate statistical method to use. We propose to use principal component analysis to complete the spectral data treatment. The soil samples came from a pedological cover made up of red–yellow Latosols: 88 samples of 11 soil profiles on four toposequences were collected; clay, organic matter, silica, iron, aluminum and titanium total contents were determined; the contents of goethite, hematite, gibbsite, and kaolinite were calculated. Diffuse reflectance Vis–NIR spectroscopy at wavelengths from 400 to 2400 nm combined with principal component analysis (PCA) was sufficiently sensitive to discriminate different Latosols. Wavelengths of 700 nm and 2200 to 2300 nm were influenced by content ratios of organic matter and iron oxides (700 nm), and kaolinite and gibbsite absorption (2200 and 2300 nm). The spectral responses were affected not only by the content of these constituents, but also by the composition of the minerals, so that the same class of Latosol may have different or similar spectral responses. The role of microaggregation is discussed.  相似文献   

The causes of land-use and land-cover change: moving beyond the myths   总被引：39，自引：0，他引：39  

Eric F. Lambin  B. L. Turner  Helmut J. Geist  Samuel B. Agbola  Arild Angelsen  John W. Bruce  Oliver T. Coomes  Rodolfo Dirzo  Günther Fischer  Carl Folke  P. S. George  Katherine Homewood  Jacques Imbernon  Rik Leemans  Xiubin Li  Emilio F. Moran  Michael Mortimore  P. S. Ramakrishnan  John F. Richards  Helle Sknes  Will Steffen  Glenn D. Stone  Uno Svedin  Tom A. Veldkamp  Coleen Vogel  Jianchu Xu 《Global Environmental Change》2001,11(4)

Common understanding of the causes of land-use and land-cover change is dominated by simplifications which, in turn, underlie many environment-development policies. This article tracks some of the major myths on driving forces of land-cover change and proposes alternative pathways of change that are better supported by case study evidence. Cases reviewed support the conclusion that neither population nor poverty alone constitute the sole and major underlying causes of land-cover change worldwide. Rather, peoples’ responses to economic opportunities, as mediated by institutional factors, drive land-cover changes. Opportunities and constraints for new land uses are created by local as well as national markets and policies. Global forces become the main determinants of land-use change, as they amplify or attenuate local factors.  相似文献